Wigner's 6-j symbols were introduced by Eugene Paul Wigner in 1940 and published in 1965.  They are defined as a sum over products of four Wigner 3-j symbols,
 
The summation is over all six mi allowed by the selection rules of the 3-j symbols.
They are closely related to the Racah W-coefficients, which are used for recoupling 3 angular momenta, although Wigner 6-j symbols have higher symmetry and therefore provide a more efficient means of storing the recoupling coefficients.  Their relationship is given by:
