Aluminium hydride

Aluminium hydride
Names
Preferred IUPAC name
Aluminium hydride
Systematic IUPAC name
Alumane
Other names
  • Alane
  • Aluminic hydride
  • Aluminium(III) hydride
  • Aluminium trihydride
  • Trihydridoaluminium
Identifiers
3D model (JSmol)
ChEBI
ChemSpider
ECHA InfoCard 100.029.139
245
UNII
  • InChI=1S/Al.3H Y
    Key: AZDRQVAHHNSJOQ-UHFFFAOYSA-N Y
  • InChI=1S/Al.3H
    Key: AZDRQVAHHNSJOQ-UHFFFAOYSA-N
  • InChI=1/Al.3H/rAlH3/h1H3
    Key: AZDRQVAHHNSJOQ-FSBNLZEDAV
  • [AlH3]
Properties
AlH3
Molar mass 30.006 g·mol−1
Appearance white crystalline solid, non-volatile, highly polymerized, needle-like crystals
Density 1.477 g/cm3, solid
Melting point 150 °C (302 °F; 423 K) starts decomposing at 105 °C (221 °F)
reacts
Solubility soluble in ether
reacts in ethanol
Thermochemistry
40.2 J/(mol·K)
30 J/(mol·K)
−11.4 kJ/mol
46.4 kJ/mol
Related compounds
Related compounds
Lithium aluminium hydride, diborane
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Y verify (what is YN ?)
Infobox references

Aluminium hydride (also known as alane and alumane) refers to a collection of inorganic compounds with the formula AlH3. As a gas, alane is a planar molecule. When generated in ether solutions, it exists as an ether adduct. Solutions of alane polymerizes to a solid, which exists in several crystallographically distinguishable forms.