Aluminium hydride
| Names | |
|---|---|
| Preferred IUPAC name
Aluminium hydride | |
| Systematic IUPAC name
Alumane | |
Other names
| |
| Identifiers | |
3D model (JSmol) |
|
| ChEBI | |
| ChemSpider | |
| ECHA InfoCard | 100.029.139 |
| 245 | |
PubChem CID |
|
| UNII | |
CompTox Dashboard (EPA) |
|
| |
| |
| Properties | |
| AlH3 | |
| Molar mass | 30.006 g·mol−1 |
| Appearance | white crystalline solid, non-volatile, highly polymerized, needle-like crystals |
| Density | 1.477 g/cm3, solid |
| Melting point | 150 °C (302 °F; 423 K) starts decomposing at 105 °C (221 °F) |
| reacts | |
| Solubility | soluble in ether reacts in ethanol |
| Thermochemistry | |
Heat capacity (C) |
40.2 J/(mol·K) |
Std molar entropy (S⦵298) |
30 J/(mol·K) |
Std enthalpy of formation (ΔfH⦵298) |
−11.4 kJ/mol |
Gibbs free energy (ΔfG⦵) |
46.4 kJ/mol |
| Related compounds | |
Related compounds |
Lithium aluminium hydride, diborane |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Infobox references | |
Aluminium hydride (also known as alane and alumane) refers to a collection of inorganic compounds with the formula AlH3. As a gas, alane is a planar molecule. When generated in ether solutions, it exists as an ether adduct. Solutions of alane polymerizes to a solid, which exists in several crystallographically distinguishable forms.