Ammonium ferric citrate

Ammonium ferric citrate
	Structure of ammonium ferric citrate
	Crystal structure of [NH4]5[Fe(C6H4O7)2]·2H2O
Names
	IUPAC name 2-Hydroxypropane-1,2,3-tricarboxylate, ammonium iron(3+) salt
	Other names Ferric ammonium citrate; Ammonium iron(III) citrate; Ammonium ferric citrate; Iron ammonium citrate; FerriSeltz
Identifiers
CAS Number	1185-57-5 ;
3D model (JSmol)	Interactive image;
ChEBI	CHEBI:31604;
ChEMBL	ChEMBL1200460 ;
ChemSpider	13804 ;
ECHA InfoCard	100.013.351
EC Number	214-686-6;
E number	E381 (antioxidants, ...)
KEGG	D01644;
PubChem CID	14457;
UNII	UVP74NG1C5 ;
CompTox Dashboard (EPA)	DTXSID9040477 ;
	InChI InChI=1S/C6H8O7.Fe.H3N/c7-3(8)1-6(13,5(11)12)2-4(9)10;;/h13H,1-2H2,(H,7,8)(H,9,10)(H,11,12);;1H3/q;+3;/p-2 Key: FRHBOQMZUOWXQL-UHFFFAOYSA-L ; InChI=1/C6H8O7.Fe.H3N/c7-3(8)1-6(13,5(11)12)2-4(9)10;;/h13H,1-2H2,(H,7,8)(H,9,10)(H,11,12);;1H3/q;+3;/p-2 Key: FRHBOQMZUOWXQL-NUQVWONBAA;
	SMILES C(C(=O)[O-])C(CC(=O)[O-])(C(=O)[O-])O.N.[Fe+3];
Properties
Chemical formula	C6H8O7⋅xFe3+⋅yNH3
Appearance	yellow crystals
Pharmacology
ATC code	V08CA07 (WHO)
Hazards
Safety data sheet (SDS)
	Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). verify (what is ?) Infobox references

Ammonium ferric citrate (also known as ferric ammonium citrate or ammoniacal ferrous citrate) has the formula [NH₄]y[Fe_x(C₆H₄O₇)]. The iron in this compound is trivalent. All three carboxyl groups and the central hydroxyl group of citric acid are deprotonated. A distinguishing feature of this compound is that it is very soluble in water, in contrast to ferric citrate which is not very soluble.

In its crystal structure each moiety of citric acid has lost four protons. The deprotonated hydroxyl group and two of the carboxylate groups ligate to the ferric center, while the third carboxylate group coordinates with the ammonium.

Names
Structure of ammonium ferric citrate
Crystal structure of [NH₄]₅[Fe(C₆H₄O₇)₂]·2H₂O
IUPAC name 2-Hydroxypropane-1,2,3-tricarboxylate, ammonium iron(3+) salt
Other names Ferric ammonium citrate Ammonium iron(III) citrate Ammonium ferric citrate Iron ammonium citrate FerriSeltz
Identifiers
CAS Number	1185-57-5^Y
3D model (JSmol)	Interactive image
ChEBI	CHEBI:31604
ChEMBL	ChEMBL1200460^N
ChemSpider	13804^N
ECHA InfoCard	100.013.351
EC Number	214-686-6
E number	E381 (antioxidants, ...)
KEGG	D01644
PubChem CID	14457
UNII	UVP74NG1C5^Y
CompTox Dashboard (EPA)	DTXSID9040477
InChI InChI=1S/C6H8O7.Fe.H3N/c7-3(8)1-6(13,5(11)12)2-4(9)10;;/h13H,1-2H2,(H,7,8)(H,9,10)(H,11,12);;1H3/q;+3;/p-2^Y Key: FRHBOQMZUOWXQL-UHFFFAOYSA-L^Y InChI=1/C6H8O7.Fe.H3N/c7-3(8)1-6(13,5(11)12)2-4(9)10;;/h13H,1-2H2,(H,7,8)(H,9,10)(H,11,12);;1H3/q;+3;/p-2 Key: FRHBOQMZUOWXQL-NUQVWONBAA
SMILES C(C(=O)[O-])C(CC(=O)[O-])(C(=O)[O-])O.N.[Fe+3]
Properties
Chemical formula	C₆H₈O₇⋅xFe³⁺⋅yNH₃
Appearance	yellow crystals
Pharmacology
ATC code	V08CA07 (WHO)
Hazards
Safety data sheet (SDS)
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). N verify (what is ^YN ?) Infobox references