Boron tribromide

Boron tribromide
Names
IUPAC name
Boron tribromide
Other names
Tribromoborane, Boron bromide
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.030.585
EC Number
  • 233-657-9
RTECS number
  • ED7400000
UNII
UN number 2692
  • InChI=1S/B.3BrH/h;3*1H/q+3;;;/p-3 Y
    Key: LKBREHQHCVRNFR-UHFFFAOYSA-K Y
  • InChI=1/BBr3/c2-1(3)4
    Key: ILAHWRKJUDSMFH-UHFFFAOYAA
  • InChI=1/B.3BrH/h;3*1H/q+3;;;/p-3
    Key: LKBREHQHCVRNFR-DFZHHIFOAX
  • BrB(Br)Br
Properties
BBr3
Molar mass 250.52 g·mol−1
Appearance Colorless to amber liquid
Odor Sharp and irritating
Density 2.643 g/cm3
Melting point −46.3 °C (−51.3 °F; 226.8 K)
Boiling point 91.3 °C (196.3 °F; 364.4 K)
Reacts violently with water and other protic solvents
Solubility Soluble in CH2Cl2, CCl4
Vapor pressure 7.2 kPa (20 °C)
1.00207
Viscosity 7.31 x 10−4 Pa s (20 °C)
Thermochemistry
0.2706 J/K
228 J/mol K
−0.8207 kJ/g
Hazards
Occupational safety and health (OHS/OSH):
Main hazards
Reacts violently with water, potassium, sodium, and alcohols; attacks metals, wood, and rubber
GHS labelling:
Danger
H300, H314, H330 Within the European Union, the following additional hazard statement (EUH014) must also be displayed on labeling: Reacts violently with water.
NFPA 704 (fire diamond)
3
0
2
Flash point Noncombustible
NIOSH (US health exposure limits):
PEL (Permissible)
None
REL (Recommended)
C 1 ppm (10 mg/m3)
IDLH (Immediate danger)
N.D.
Safety data sheet (SDS) ICSC 0230
Related compounds
Related compounds
Boron trifluoride
Boron trichloride
Boron triiodide
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
N verify (what is YN ?)
Infobox references

Boron tribromide, BBr3, is a colorless, fuming liquid compound containing boron and bromine. Commercial samples usually are amber to red/brown, due to weak bromine contamination. It is decomposed by water and alcohols.