Carbonyl diazide

Carbonyl diazide
Names
IUPAC name
Carbonyl diazide
Other names
Carbonyl azide,
Carbonic diazide,
Azido ketone
Identifiers
3D model (JSmol)
ChemSpider
  • InChI=1S/CN6O/c2-6-4-1(8)5-7-3
    Key: VQXINLNPICQTLR-UHFFFAOYSA-N
  • C(=O)(N=[N+]=[N-])N=[N+]=[N-]
Properties
CO(N3)2
Molar mass 112.052 g·mol−1
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Infobox references

Carbonyl diazide is a chemical compound with the chemical formula CO(N3)2. In terms of its structure, it can be described as two azide groups −N3 covalently attached to the carbonyl group −C(=O)− by single bonds. It can be prepared by way of the reaction between triphosgene and tetra-n-butylammonium azide, in a dimethyl or diethyl solution.

The first synthesis of carbonyl diazide was reported in 1894, although there have been multiple alternative syntheses since then.