Cerium(III) chloride

Cerium(III) chloride
Names
IUPAC names
Cerium(III) chloride
Cerium trichloride
Other names
Cerous chloride
Identifiers
3D model (JSmol)
ChEBI
ChemSpider
ECHA InfoCard 100.029.298
EC Number
  • 232-227-8
1828
UNII
  • InChI=1S/Ce.3ClH/h;3*1H/q+3;;;/p-3 Y
    Key: VYLVYHXQOHJDJL-UHFFFAOYSA-K Y
  • InChI=1/Ce.3ClH/h;3*1H/q+3;;;/p-3
    Key: VYLVYHXQOHJDJL-DFZHHIFOAZ
  • [Cl-].[Cl-].[Cl-].[Ce+3]
Properties
CeCl3
Molar mass 246.48 g/mol (anhydrous)
372.58 g/mol (heptahydrate)
Appearance fine white powder
Density 3.97 g/cm3
Melting point 817 °C (1,503 °F; 1,090 K) (anhydrous)
90 °C (heptahydrate, decomposes)
Boiling point 1,727 °C (3,141 °F; 2,000 K)
Solubility soluble in alcohol
+2490.0·10−6 cm3/mol
Structure
hexagonal (UCl3 type), hP8
P63/m, No. 176
Tricapped trigonal prismatic
(nine-coordinate)
Hazards
GHS labelling:
Danger
H315, H318, H319, H335, H410
P261, P264, P271, P273, P280, P302+P352, P304+P340, P305+P351+P338, P310, P312, P321, P332+P313, P337+P313, P362, P391, P403+P233, P405, P501
Flash point Non-flammable
Related compounds
Other anions
Cerium(III) oxide
Cerium(III) fluoride
Cerium(III) bromide
Cerium(III) iodide
Other cations
Lanthanum(III) chloride
Praseodymium(III) chloride
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
N verify (what is YN ?)
Infobox references

Cerium(III) chloride (CeCl3), also known as cerous chloride or cerium trichloride, is a compound of cerium and chlorine. It is a white hygroscopic salt; it rapidly absorbs water to form hydrates, which may be of variable composition.The hexa- and heptahydrate CeCl3·7H2O are known. All forms are highly soluble in water, and the anhydrous derivative is soluble in ethanol and acetone.