Cordierite

Cordierite
General
CategoryCyclosilicate
Formula(Mg,Fe)2Al4Si5O18
IMA symbolCrd
Strunz classification9.CJ.10
Dana classification61.02.01.01
Cordierite group
Crystal systemOrthorhombic
Crystal classDipyramidal (mmm)
H-M symbol: (2/m 2/m 2/m)
Space groupCccm
Unit cella = 17.079 Å,
b = 9.730 Å,
c = 9.356 Å; Z = 4
Identification
ColorBlue, smoky blue, bluish violet; greenish, yellowish brown, gray; colorless to very pale blue in thin section in transmitted light
Crystal habitPseudo-hexagonal prismatic twins, as imbedded grains, and massive
TwinningCommon on {110}, {130}, simple, lamellar, cyclical
CleavageFair on {100}, poor on {001} and {010}
FractureSubconchoidal
TenacityBrittle
Mohs scale hardness7–7.5
LusterGreasy or vitreous
StreakWhite
DiaphaneityTransparent to translucent
Specific gravity2.57–2.66
Optical propertiesUsually optically (-), sometimes (+); 2V = 0–90°
Refractive indexnα = 1.527 – 1.560 nβ = 1.532 – 1.574 nγ = 1.538 – 1.578 Indices increase with Fe content.
PleochroismX = pale yellow, green; Y = violet, blue-violet; Z = pale blue
Fusibilityon thin edges
Diagnostic featuresResembles quartz, can be distinguished by pleochroism. Can be distinguished from corundum by its lower hardness
References

Cordierite (mineralogy) or iolite (gemology) is a magnesium iron aluminium cyclosilicate. Iron is almost always present, and a solid solution exists between Mg-rich cordierite and Fe-rich sekaninaite with a series formula: (Mg,Fe)2Al3(Si5AlO18) to (Fe,Mg)2Al3(Si5AlO18). A high-temperature polymorph exists, indialite, which is isostructural with beryl and has a random distribution of Al in the (Si,Al)6O18 rings. Cordierite is also synthesized and used in high temperature applications such as catalytic converters and pizza stones.