Mottramite

Mottramite
General
CategoryVanadate minerals
FormulaPbCu(VO4)(OH)
IMA symbolMott
Strunz classification8.BH.40
Dana classification41.5.2.2
Crystal systemOrthorhombic
Crystal classDipyramidal (mmm)
H-M symbol: (2/m 2/m 2/m)
Space groupPnma
Unit cella = 7.68 Å, b = 9.27 Å,
c = 6.03 Å; Z = 4
Identification
Formula mass402.69 g/mol
ColourGrass-green, olive-green, yellow-green, siskin-green, blackish brown, nearly black
Crystal habitEncrustations, aggregates of plume-like forms and radial crystals
CleavageNone observed
FractureIrregular/uneven, sub-conchoidal
TenacityBrittle
Mohs scale hardness3 – 3+12
LustreGreasy
StreakYellowish green
DiaphaneityTransparent, opaque
Specific gravity5.9
Optical propertiesUsually biaxial (−) rarely biaxial (+)
Refractive indexnα = 2.170(2) nβ = 2.260(2) nγ = 2.320(2)
Birefringenceδ = 0.150
PleochroismVisible X=Y= canary yellow to greenish yellow, Z= brownish yellow
2V angleMeasured: 73°, calculated: 46°
DispersionStrong r > v rarely r < v
SolubilityReadily soluble in acids
Common impuritiesZinc
References

Mottramite is an orthorhombic anhydrous vanadate hydroxide mineral, PbCu(VO4)(OH), at the copper end of the descloizite subgroup. It was formerly called cuprodescloizite or psittacinite (this mineral characterized in 1868 by Frederick Augustus Genth). Duhamelite is a calcium- and bismuth-bearing variety of mottramite, typically with acicular habit.

Mottramite is a member of the adelite-descloizite group. Mottramite, which is a copper rich member, forms a series with descloizite, which is a zinc rich member. These two minerals usually contain significant percentages of both copper and zinc and are seldom pure. Mottramite also forms a series with duftite.

It was discovered in 1876 and named for the locality, Mottram St Andrew, Cheshire, England, where ore was stockpiled, although it was probably mined from Pim Hill Mine, Shrewsbury, Shropshire, England.