Dibenzocyclooctatetraene

Dibenzocyclooctatetraene
Names
Other names
Dibenzo[a,e]cyclooctatetraene, Dibenzo[a,e]cyclooctene, DBCOT
Identifiers
3D model (JSmol)
ChemSpider
  • InChI=1S/C16H12/c1-2-6-14-11-12-16-8-4-3-7-15(16)10-9-13(14)5-1/h1-12H/b10-9-,12-11-,13-9?,14-11?,15-10?,16-12?
    Key: VGQWCQNHAMVTJY-RKUAQPHYSA-N
  • C1=CC=C/2C(=C1)/C=C\C3=CC=CC=C3/C=C2
Properties
C16H12
Molar mass 204.272 g·mol−1
Appearance colorless crystals
Melting point 108.5–109.2 °C (227.3–228.6 °F; 381.6–382.3 K)
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Infobox references

Dibenzocyclooctatetraene is an organic compound with the formula (C6H4)2(C2H2)2. It is the bis(benzo) derivative of both cyclooctatetraene and 1,5-cyclooctadiene. The compound has received much attention as a strongly chelating diolefin ligand.

The compound can be made by coupling of xylylene dibromide to dibenzocyclooctane, which then can be converted to the diolefin.