Dichlorine trioxide

Dichlorine trioxide
Names
IUPAC name
dichlorine trioxide
Other names
chlorine trioxide
chlorine chlorate
chlorine(I,V) oxide
Identifiers
3D model (JSmol)
ChemSpider
  • InChI=1S/Cl2O3/c1-5-2(3)4 Y
    Key: SAUMVKNLVQDHMJ-UHFFFAOYSA-N Y
  • InChI=1/Cl2O3/c1-5-2(3)4
    Key: SAUMVKNLVQDHMJ-UHFFFAOYAS
  • ClOCl(=O)=O
Properties
Cl2O3
Molar mass 118.903 g/mol
Appearance dark brown solid
Melting point explodes below 0 °C
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
N verify (what is YN ?)
Infobox references

Dichlorine trioxide, Cl2O3, is a chlorine oxide. It is a dark brown solid discovered in 1967 which is explosive even below 0 °C. It is formed by the low-temperature photolysis of ClO2 and is formed along with Cl2O6, Cl2 and O2. Its structure is believed to be OClClO2 with possible isomers such as ClOClO2. The isomer having a structure of OCl–O–ClO would be the theoretical anhydride of chlorous acid.