Disilyne
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| Names | |||
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| IUPAC name
Disilyne | |||
| Identifiers | |||
3D model (JSmol) |
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| ChemSpider | |||
PubChem CID |
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CompTox Dashboard (EPA) |
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| Properties | |||
| H2Si2 | |||
| Molar mass | 58.186 g·mol−1 | ||
| Related compounds | |||
Related compounds |
Acetylene methylacetylene | ||
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Infobox references | |||
Disilyne is a low valent silicon compound with the chemical formula Si2R2 where oxidation state of Si is +1. Several isomers are possible, but none are sufficiently stable to be of practical value. Substituted disilynes contain a formal silicon–silicon triple bond and as such are sometimes written R2Si2 (where R is a substituent group). They are the silicon analogues of alkynes.
The term silyne has two diverse meanings. Some chemists use it to refer to compounds containing a silicon–silicon triple bond, by analogy to the carbon–carbon triple bond in alkynes, whereas others use the term to refer to compounds containing a silicon–carbon triple bond by analogy to silene, which often refers to compounds containing silicon–carbon double bonds. The term polysilyne can refer to the layer polymer (SiH)n or substituted derivatives.