Gold(I,III) chloride

Gold(I,III) chloride
Names
Systematic IUPAC name
tetra-μ-chlorotetrachlorotetragold
Other names
Mixed gold chloride, Tetragold octachloride
Identifiers
3D model (JSmol)
  • InChI=1S/4Au.4ClH.4Cl/h;;;;4*1H;;;;/q;;2*+2;;;;;;;;/p-4 N
    Key: NWBJVUUFMJPGPV-UHFFFAOYSA-J N
  • Cl[Au]1(Cl)[Cl][Au][Cl][Au](Cl)(Cl)[Cl][Au][Cl]1
  • [Cl-].[Cl-].[Cl-].[Cl-].[Cl-].[Cl-].[Cl-].[Cl-].[Au+].[Au+].[Au+3].[Au+3]
Properties
Au
4
Cl
8
Molar mass 1071.490 g mol−1
Appearance black crystals
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
N verify (what is YN ?)
Infobox references

Gold(I,III) chloride is the inorganic compound with the chemical formula Au4Cl8. It is a mixed valence compound as it contains gold in two oxidation states; square-planar gold(III) and almost linear gold(I). The compound, which is black, is photosensitive as well as air- and moisture-sensitive.