Hellyerite

Hellyerite
Zaratite (emerald-green coating), hellyerite (powder-blue) and heazlewoodite (light bronze)
General
CategoryCarbonate mineral
FormulaNiCO3·5.5(H2O)
IMA symbolHy
Strunz classification5.CA.20
Crystal systemMonoclinic
Crystal classPrismatic (2/m)
(same H-M symbol)
Space groupC2/c
Unit cella = 10.77, b = 7.29
c = 18.68 [Å]; β = 94°: Z = 8
Identification
ColorPale blue
Crystal habitAs crystal fragments and microcrystalline coatings
TwinningFine lamellar parallel to cleavage
CleavageOne perfect, two good at 112° to each other and perpendicular to the perfect cleavage
Mohs scale hardness2.5
LusterVitreous
DiaphaneitySemitransparent
Specific gravity1.97
Optical propertiesBiaxial (−)
Refractive indexnα = 1.455 nβ = 1.503 nγ = 1.549
Birefringenceδ = 0.094
PleochroismX = Y = very pale greenish blue; Z = pale greenish blue
2V angleMeasured: 85°
Alters toDecomposes on air exposure
References

Hellyerite, NiCO3·6(H2O), is a hydrated nickel carbonate mineral. It is light blue to bright green in colour, has a hardness of 2.5, a vitreous luster, a white streak and crystallises in the monoclinic system. The crystal habit is as platy and mammillary encrustations on its matrix. It is a pentahydrate according to X-ray crystallography. The solid consists of [Ni2(CO3)2(H2O)8] subunits with an extra pair of water of hydration.