Iron(II) carbonate

iron(II) carbonate
Names
Other names
ferrous carbonate
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.008.418
E number E505 (acidity regulators, ...)
UNII
  • InChI=1S/CH2O3.Fe/c2-1(3)4;/h(H2,2,3,4);/q;+2/p-2
    Key: RAQDACVRFCEPDA-UHFFFAOYSA-L
  • C(=O)([O-])[O-].[Fe+2]
Properties
FeCO3
Molar mass 115.854 g/mol
Appearance white powder or crystals
Density 3.9 g/cm3
Melting point decomposes
0.0067 g/L; Ksp = 1.28 × 10−11
3.13×1011
+11,300·10−6 cm3/mol
Structure
Hexagonal scalenohedral / Trigonal (32/m)
Space group: R 3c, a = 4.6916 Å, c = 15.3796 Å
6
Related compounds
Other anions
iron(II) sulfate
Other cations
copper(II) carbonate, zinc carbonate
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Infobox references

Iron(II) carbonate, or ferrous carbonate, is a chemical compound with formula FeCO
3
, that occurs naturally as the mineral siderite. At ordinary ambient temperatures, it is a green-brown ionic solid consisting of iron(II) cations Fe2+
and carbonate anions CO2−
3
. The compound crystallizes in the same motif as calcium carbonate. In this motif, the carbonate dianion is nearly planar. Its three oxygen atoms each bind to two Fe(II) centers, such that the Fe has an octahedral coordination geometry.