Lead(IV) chloride
| Lead tetrachloride contaminated with lead(II) chloride | |
| Names | |
|---|---|
| IUPAC name Lead(IV) chloride | |
| Systematic IUPAC name Tetrachloroplumbane | |
| Identifiers | |
| 3D model (JSmol) | |
| ChemSpider | |
| PubChem CID | |
| CompTox Dashboard (EPA) | |
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| Properties | |
| PbCl4 | |
| Molar mass | 349.012 g/mol | 
| Appearance | yellow oily liquid | 
| Density | 3.2 g⋅cm−3 | 
| Melting point | −15 °C (5 °F; 258 K) stable below 0 °C (32 °F; 273 K) | 
| Boiling point | 50 °C (122 °F; 323 K) decomposes | 
| Reacts | |
| Solubility | hydrochloric acid | 
| Structure | |
| 4 | |
| tetrahedral | |
| Thermochemistry | |
| Std enthalpy of formation (ΔfH⦵298) | −328.9 kJ/mol | 
| Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). Infobox references | |
Lead tetrachloride, also known as lead(IV) chloride, has the molecular formula PbCl4. It is a yellow, oily liquid which is stable below 0 °C, and decomposes at 50 °C. It has a tetrahedral configuration, with lead as the central atom. The Pb–Cl covalent bonds have been measured to be 247 pm and the bond energy is 243 kJ⋅mol−1.