Methoxymethylenetriphenylphosphorane

Methoxymethylene­triphenylphosphorane
Names
IUPAC name
Methoxymethylidene(triphenyl)-λ5-phosphane
Identifiers
3D model (JSmol)
ChemSpider
  • InChI=1S/C20H19OP/c1-21-17-22(18-11-5-2-6-12-18,19-13-7-3-8-14-19)20-15-9-4-10-16-20/h2-17H,1H3
    Key: DYROHZMICXBUMX-UHFFFAOYSA-N
  • COC=P(C1=CC=CC=C1)(C2=CC=CC=C2)C3=CC=CC=C3
Properties
C20H19OP
Molar mass 306.345 g·mol−1
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Infobox references

Methoxymethylenetriphenylphosphorane is a Wittig reagent used for the homologization of aldehydes, and ketones to extended aldehydes, an organic reaction first reported in 1958. The reagent is generally prepared and used in situ. It has blood-red color, indicative of destabilized ylides.