Periodic acid

Periodic acid
Orthoperiodic acid
Metaperiodic acid
Orthoperiodic acid
Names
Other names
  • Paraperiodic acid
  • Iodic(VII) acid
  • Hydrogen periodate
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.030.839
EC Number
  • 236-585-6
UNII
UN number UN3085
  • (orthoperiodic): InChI=I=1S/H5IO6/c2-1(3,4,5,6)7/h(H5,2,3,4,5,6,7)
    Key: TWLXDPFBEPBAQB-UHFFFAOYSA-N
  • (metaperiodic): InChI=1/HIO4/c2-1(3,4)5/h(H,2,3,4,5)
    Key: KHIWWQKSHDUIBK-UHFFFAOYAH
  • (orthoperiodic): OI(=O)(O)(O)(O)O
  • (metaperiodic): O[I+3]([O-])([O-])[O-]
Properties
HIO4 (metaperiodic)
H5IO6 (orthoperiodic)
Molar mass 190.91 g/mol (HIO4)
227.941 g/mol (H5IO6)
Appearance Colourless crystals
Melting point 128.5 °C (263.3 °F; 401.6 K)
Solubility soluble in water, alcohols
Acidity (pKa) pKa1 = 3.29
pKa2 = 8.31
pKa3 = 11.60
Conjugate base Periodate
Hazards
GHS labelling:
Danger
H271, H314, H372, H400
P210, P260, P273, P303+P361+P353, P305+P351+P338
NFPA 704 (fire diamond)
Safety data sheet (SDS) External MSDS
Related compounds
Other anions
Other cations
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
N verify (what is YN ?)
Infobox references

Periodic acid (/ˌpɜːrˈɒdɪk/ per-eye-OD-ik) is an oxoacid of iodine. It can exist in two forms: orthoperiodic acid, with the chemical formula H5IO6, and metaperiodic acid, which has the formula HIO4. Periodic acids are colourless crystals. Periodic acid features iodine in the highest oxidation state of +7.

Periodic acid was discovered by Heinrich Gustav Magnus and C. F. Ammermüller in 1833.