Polyetherimide

Polyetherimide
Names
IUPAC name
benzene-1,3-diamine; 5-[4-[2-[4-[(1,3-dioxo-2-benzofuran-5-yl)oxy]phenyl]propan-2-yl]phenoxy]-2-benzofuran-1,3-dione
Other names
PEI, Ultem
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.126.800
  • CC(C)(c1ccc(Oc2ccc3c(c2)C(=O)OC3=O)cc1)c1ccc(Oc2ccc3c(c2)C(=O)OC3=O)cc1.Nc1cccc(N)c1
Properties
(C37H24O6N2)n
Molar mass Variable
Appearance Amber-to-transparent solid
Density 1.27 g/cm3
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
N verify (what is YN ?)
Infobox references
Polyetherimide
Physical properties
Density (ρ)1.27 g/cc
Water absorption—over 24 hours0.25%
Mechanical properties
Tensile strength (σt)115 MPa
Elongation (ε) at break60-80%
Izod impact strength25-60 J/m
Thermal properties
Glass transition temperature (Tg)215 C
Heat deflection temperature at 0.46 MPa / 66 psi210 C
Vicat softening point220 C
Upper working temperature375 C
Lower working temperature365 C
Data via Sastri et al., 2014.

Polyetherimide (PEI; branded as Ultem) is an amorphous, amber-to-transparent thermoplastic with characteristics similar to the related plastic PEEK. When comparing PEI to PEEK, the former is cheaper but has lower impact strength and a tighter temperature range.

PEI plastics were first introduced into the market by General Electric (GE) in 1982 under the trade name Ultem resulting from the work of J.G. Wirth's research team in the early 1970s.

Due to its adhesive properties and chemical stability it became a popular bed material for FFF 3D printers.