Potassium metabisulfite
| Names | |
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| Other names 
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| Identifiers | |
| 3D model (JSmol) | |
| ChemSpider | |
| ECHA InfoCard | 100.037.072 | 
| E number | E224 (preservatives) | 
| PubChem CID | |
| RTECS number | 
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| UNII | |
| CompTox Dashboard (EPA) | |
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| Properties | |
| K2O5S2 | |
| Molar mass | 222.31 g·mol−1 | 
| Appearance | White crystalline powder | 
| Odor | Pungent (sulfur dioxide) | 
| Density | 2.34 g/cm3 (solid) | 
| Melting point | 190 °C (374 °F; 463 K) decomposes | 
| 450 g/L (20 °C) | |
| Solubility | Insoluble in ethanol | 
| Hazards | |
| Occupational safety and health (OHS/OSH): | |
| Main hazards | Irritant, asthma risk | 
| GHS labelling: | |
| Danger | |
| H315, H318, H335 | |
| P261, P264, P271, P280, P302+P352, P304+P340, P305+P351+P338, P310, P312, P321, P332+P313, P362, P403+P233, P405, P501 | |
| NFPA 704 (fire diamond) | |
| Safety data sheet (SDS) | ICSC 1175 | 
| Related compounds | |
| Other anions | Potassium bisulfite Potassium sulfite | 
| Other cations | Sodium metabisulfite | 
| Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). Infobox references | |
Potassium metabisulfite, K2S2O5, also known as potassium pyrosulfite, is a white crystalline powder with a pungent odour. It is mainly used as an antioxidant or chemical sterilant. As a disulfite, it is chemically very similar to sodium metabisulfite, with which it is sometimes used interchangeably. Potassium metabisulfite has a monoclinic crystal structure.