Realgar

Realgar
Realgar crystals, Royal Reward Mine, King County, Washington, US
General
CategorySulfide mineral
FormulaAs4S4 or AsS
IMA symbolRlg
Strunz classification2.FA.15a
Crystal systemMonoclinic
Crystal classPrismatic (2/m)
(same H-M symbol)
Space groupP21/n (no. 14)
Unit cella = 9.325(3) Å
b = 13.571(5) Å
c = 6.587(3) Å
β = 106.43°; Z = 16
Identification
ColorRed to yellow-orange; in polished section, pale gray, with abundant yellow to red internal reflections
Crystal habitPrismatic striated crystals; more commonly massive, coarse to fine granular, or as incrustations
TwinningContact twins on {100}
CleavageGood on {010}; less so on {101}, {100}, {120}, and {110}
TenacitySectile, slightly brittle
Mohs scale hardness1.5–2
LusterResinous to greasy
StreakRed-orange to red
DiaphaneityTransparent
Specific gravity3.56
Optical propertiesBiaxial (−)
Refractive indexnα = 2.538
nβ = 2.684
nγ = 2.704
Birefringenceδ = 0.166
PleochroismNearly colorless to pale golden yellow
2V angle40°
Dispersionr > v, very strong
Other characteristicsToxic and carcinogenic. Disintegrates on long exposure to light to a powder composed of pararealgar or arsenolite and orpiment.
References

Realgar (/riˈælɡɑːr, -ɡər/ ree-AL-gar, -gər), also known as arsenic blende, ruby sulphur or ruby of arsenic, is an arsenic sulfide mineral with the chemical formula α-As4S4. It is a soft, sectile mineral occurring in monoclinic crystals, or in granular, compact, or powdery form, often in association with the related mineral, orpiment (As2S3). It is orange-red in color, melts at 320 °C, and burns with a bluish flame releasing fumes of arsenic and sulfur. Realgar is soft with a Mohs hardness of 1.5 to 2 and has a specific gravity of 3.5. Its streak is orange colored. It is trimorphous with pararealgar and bonazziite.