Selenocyanate
| Identifiers | |
|---|---|
3D model (JSmol) |
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| 1848016 | |
| ChEBI | |
| ChEMBL | |
| ChemSpider | |
| 81789 | |
PubChem CID |
|
CompTox Dashboard (EPA) |
|
| |
| |
| Properties | |
| CNSe− | |
| Molar mass | 104.990 g·mol−1 |
| Related compounds | |
Related compounds |
thiocyanate; cyanate |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Infobox references | |
A selenocyanate is an ion or chemical compound that contains the -SeCN group, which could be in the form of an anion, SeCN−. Organic selenocyanates also exist.
Some complex ions with transition metals such as silver and mercury (mercuriselenocyanates) are known. Mercuriselenocyanate salts also include K, Fe, Co, Ni, Cu, Zn, and Cd. Complex ions include Fe(NCSe)63−, Fe(NCSe)64−, Fe(NCSe)42−, Co(NCSe)64−, Co(NCSe)42−, Ni(NCSe)64−, Zn(NCSe)64−, Rh(NCSe)64−, Pd(NCSe)42−, Ag(SeCN)2−, Cd(NCSe)42−, Cd(NCSe)64−, Dy(NCSe)63−, Ho(NCSe)63−, Er(NCSe)63−, Pt(NCSe)62−, Au(NCSe)4−, and Hg(NCSe)42−.
For hard metals, the negative charge is on the nitrogen atom which coordinates with the metal atom. Examples include Ti(NCSe)62−, V(NCSe)63−, VO(NCSe)42−, Cr(NCSe)63−, Mn(NCSe)42−, Mn(NCSe)42−, Y(NCSe)63−, Zr(NCSe)62−, Mo(NCSe)63−, Pr(NCSe)63−, Nd(NCSe)63−, Sm(NCSe)63−, Hf(NCSe)62−, Re2(NCSe)82−, Pa(NCSe)84− and U(NCSe)84−.