Smoky quartz

Smoky quartz
General
CategoryTectosilicates, quartz variety
FormulaSiO2
Strunz classification04.DA.05
Dana classification75.01.03.01
Crystal systemα-quartz: trigonal trapezohedral class 3 2; β-quartz: hexagonal 622
Space groupTrigonal 32
Unit cella = 4.9133 Å, c = 5.4053 Å; Z=3
Identification
ColourBrown to grey, opaque
Crystal habit6-sided prism ending in 6-sided pyramid (typical), drusy, fine-grained to microcrystalline, massive
TwinningCommon Dauphine law, Brazil law and Japan law
Cleavage{0110} none
FractureConchoidal
TenacityBrittle
Mohs scale hardness7 – lower in impure varieties (defining mineral)
LustreVitreous – waxy to dull when massive
StreakWhite
DiaphaneityTransparent to nearly opaque
Specific gravity2.65; variable 2.59–2.63 in impure varieties
Optical propertiesUniaxial (+)
Refractive indexnω = 1.543–1.545
nε = 1.552–1.554
Birefringence+0.009 (B-G interval)
Pleochroismweak, from red-brown to green-brown
Melting point1670 °C (β tridymite) 1713 °C (β cristobalite)
SolubilityInsoluble at STP; 1 ppmmass at 400 °C and 500 lb/in2 to 2600 ppmmass at 500 °C and 1500 lb/in2
Other characteristicslattice: hexagonal, Piezoelectric, may be triboluminescent, chiral (hence optically active if not racemic)
References

Smoky quartz is a brownish grey, translucent variety of quartz that ranges in clarity from almost complete transparency to an almost-opaque brownish-gray or black crystals. The color of smoky quartz is produced when natural radiation, emitted from the surrounding rock, activates color centers around aluminum impurities within the crystalline quartz.