Sodium methanethiolate

Sodium methanethiolate
Names
Preferred IUPAC name
Sodium methanethiolate
Other names
sodium thiomethoxide, sodium methyl mercaptide, sodium thiomethylate, methanethiol sodium salt, methyl mercaptan sodium salt, MeSNa
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.023.609
EC Number
  • 225-969-9
UNII
  • InChI=1S/CH4S.Na/c1-2;/h2H,1H3;/q;+1/p-1 Y
    Key: RMBAVIFYHOYIFM-UHFFFAOYSA-M Y
  • InChI=1/CH4S.Na/c1-2;/h2H,1H3;/q;+1/p-1
  • [Na+].[S-]C
Properties
CH3NaS
Molar mass 70.08 g·mol−1
Appearance white
Density 1.43 g/cm3
Melting point 88–90 °C (190–194 °F; 361–363 K)
soluble
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
N verify (what is YN ?)
Infobox references

Sodium methanethiolate or sodium thiomethoxide is an organosulfur compound with the formula CH3SNa. It is the sodium salt of the conjugate base of methanethiol. This compound is commercially available as a white solid that is soluble in polar organic solvents. Sodium methanethiolate is a reagent in organic synthesis and a byproduct of some industrial processes. Hydrolysis of sodium methanethiolate, e.g. in humid air, produces methanethiol, which has a low odor threshold and a noxious "rotten egg" smell.