Sodium perborate
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| Other names
Sodium peroxoborate, PBS-1 ("monohydrate"), PBS-4 ("tetrahydrate") | |
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3D model (JSmol) |
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| ChEBI | |
| ChemSpider | |
| ECHA InfoCard | 100.035.597 |
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PubChem CID |
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| UN number | 1479 |
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| Properties | |
| NaBO3·nH2O | |
| Molar mass | 99.815 g/mol ("monohydrate"); 153.86 g/mol ("tetrahydrate") |
| Appearance | White powder |
| Odor | Odorless |
| Melting point | 63 °C (145 °F; 336 K) ("tetrahydrate") |
| Boiling point | 130 to 150 °C (266 to 302 °F; 403 to 423 K) ("tetrahydrate", decomposes) |
| 2.15 g/(100 mL) ("tetrahydrate", 18 °C) | |
| Pharmacology | |
| A01AB19 (WHO) | |
| Hazards | |
| NFPA 704 (fire diamond) | |
| Flash point | Non-flammable |
| Safety data sheet (SDS) | ICSC 1046 |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Infobox references | |
Sodium perborate are chemical compounds with chemical formula [Na+]2[B2O4(OH)4]2−(H2O)x. Commonly encountered salts are the anhydrous form (x = 0) and as a hexahydrate (x = 6). These two species are sometimes called, respectively, "monohydrate" or PBS-1 and "tetrahydrate" or PBS-4, after the historic assumption that NaBO3 would be the anhydrous form). Both the anhydrous and hexahydrate salts are white, odorless, water-soluble solids.
Peroxyborates are widely used in laundry detergents, as one of the peroxide-based bleaches.
Sodium perborate was first obtained in 1898, independently, by Sebastian Tanatar and by P. Melikoff and L. Pissadewsky; the researchers prepared sodium perborate by treating sodium borate with a solution of hydrogen peroxide and sodium hydroxide, but Tanatar also obtained sodium perborate by electrolysis of a solution of sodium borate.