SPANphos

SPANphos
Names
	Preferred IUPAC name (4,4,4′,4′,6,6′-Hexamethyl-3,3′,4,4′-tetrahydro-2,2′-spirobi[[1]benzopyran]-8,8′-diyl)bis(diphenylphosphane)
Identifiers
CAS Number	556797-94-5 ;
3D model (JSmol)	Interactive image;
PubChem CID	12103420;
CompTox Dashboard (EPA)	DTXSID501336643 ;
	InChI InChI=1S/C47H46O2P2/c1-33-27-39-43(41(29-33)50(35-19-11-7-12-20-35)36-21-13-8-14-22-36)48-47(31-45(39,3)4)32-46(5,6)40-28-34(2)30-42(44(40)49-47)51(37-23-15-9-16-24-37)38-25-17-10-18-26-38/h7-30H,31-32H2,1-6H3 Key: RQMTZMWXNZQOPD-UHFFFAOYSA-N;
	SMILES CC1=CC(=C2C(=C1)C(CC3(O2)CC(C4=CC(=CC(=C4O3)P(C5=CC=CC=C5)C6=CC=CC=C6)C)(C)C)(C)C)P(C7=CC=CC=C7)C8=CC=CC=C8;
Properties
Chemical formula	C47H46O2P2
Molar mass	704.814 g/mol
	Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). verify (what is ?) Infobox references

SPANphos is an organophosphorus compound used as a ligand in organometallic and coordination chemistry. The compound is a rare example of a trans-spanning ligand and rigidly links mutually trans coordination sites. By virtue of its C₂-symmetric backbone, SPANphos forms a chiral cavity over the face of a square planar complexes, e.g. in MCl₂(SPANphos) (M = Pd, Pt).