Sulfuryl fluoride

Sulfuryl fluoride
Names
IUPAC name
Sulfuryl fluoride
Other names
Sulfonyl fluoride; Sulfur dioxide difluoride; Sulphuryl fluoride; Sulfuryl difluoride; Vikane; Zythor
Identifiers
3D model (JSmol)
ChEBI
ChemSpider
ECHA InfoCard 100.018.437
UNII
  • InChI=1S/F2O2S/c1-5(2,3)4 Y
    Key: OBTWBSRJZRCYQV-UHFFFAOYSA-N Y
  • InChI=1/F2O2S/c1-5(2,3)4
    Key: OBTWBSRJZRCYQV-UHFFFAOYAJ
  • FS(F)(=O)=O
Properties
SO2F2
Molar mass 102.06 g/mol
Appearance colourless gas
Odor odorless
Density 4.172 g/L (gas), 1.632 g/mL (liquid under compressed gas at 0 °C)
Melting point −124.7 °C (−192.5 °F; 148.5 K)
Boiling point −55.4 °C (−67.7 °F; 217.8 K)
0.2% (0°C)
Solubility in other solvents SO2
Vapor pressure 15.8 atm (21°C)
Structure
tetrahedral
Hazards
Occupational safety and health (OHS/OSH):
Main hazards
neurotoxin
NFPA 704 (fire diamond)
3
0
1
Lethal dose or concentration (LD, LC):
991 ppm (rat, 4 hr)
1200 ppm (mouse, 1 hr)
5000 ppm (rabbit, 1 hr)
NIOSH (US health exposure limits):
PEL (Permissible)
TWA 5 ppm (20 mg/m3)
REL (Recommended)
TWA 5 ppm (20 mg/m3) ST 10 ppm (40 mg/m3)
IDLH (Immediate danger)
200 ppm
Related compounds
Other anions
SO2Cl2,
SO2ClF
Other cations
SeO2F2
Related compounds
SF6,
SO3
SO2F3
CrO2F2
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Infobox references

Sulfuryl fluoride (also spelled sulphuryl fluoride) is an inorganic compound with the formula SO2F2. It is an easily condensed gas and has properties more similar to sulfur hexafluoride than sulfuryl chloride, being resistant to hydrolysis even up to 150 °C. It is neurotoxic and a potent greenhouse gas, but is widely used as a fumigant insecticide to control termites.