Tetrabutylammonium bromide

Tetra-n-butylammonium bromide
Names
Preferred IUPAC name
N,N,N-Tributylbutan-1-aminium bromide
Other names
  • Tetra-n-butylammonium bromide
  • TBAB
Identifiers
3D model (JSmol)
ChEBI
ChEMBL
ChemSpider
ECHA InfoCard 100.015.182
EC Number
  • 216-699-2
UNII
  • InChI=1S/C16H36N.BrH/c1-5-9-13-17(14-10-6-2,15-11-7-3)16-12-8-4;/h5-16H2,1-4H3;1H/q+1;/p-1 Y
    Key: JRMUNVKIHCOMHV-UHFFFAOYSA-M Y
  • InChI=1/C16H36N.BrH/c1-5-9-13-17(14-10-6-2,15-11-7-3)16-12-8-4;/h5-16H2,1-4H3;1H/q+1;/p-1
    Key: JRMUNVKIHCOMHV-REWHXWOFAC
  • [Br-].CCCC[N+](CCCC)(CCCC)CCCC
Properties
C16H36BrN
Molar mass 322.368 g/mol
Appearance White solid
Density 1.18 g/cm3
Melting point 125 °C (257 °F; 398 K) Decomposes at 133°C
600 g/L (20 °C)
Solubility Soluble in dichloromethane and ethanol, slightly soluble in toluene
Hazards
Occupational safety and health (OHS/OSH):
Main hazards
Harmful
GHS labelling:
Warning
H302, H315, H319, H335, H411, H412
P261, P264, P270, P271, P273, P280, P301+P312, P302+P352, P304+P340, P305+P351+P338, P312, P321, P330, P332+P313, P337+P313, P362, P391, P403+P233, P405, P501
Related compounds
Other anions
Tetrabutylammonium tribromide, Tetra-n-butylammonium fluoride, Tetrabutylammonium chloride, Tetra-n-butylammonium iodide, Tetrabutylammonium hydroxide
Other cations
Tetramethylammonium bromide, Tetraethylammonium bromide
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Y verify (what is YN ?)
Infobox references

Tetrabutylammonium bromide (TBAB) is a quaternary ammonium salt with a bromide commonly used as a phase transfer catalyst. It is used to prepare many other tetrabutylammonium salts by salt metathesis reactions. The anhydrous form is a white solid.

In addition to being cheap, tetrabutylammonium bromide is also environmentally friendly, has a greater degree of selectivity, is operationally simple, non-corrosive, and can be recycled easily as well.