Tetraethyl orthosilicate
| Names | |
|---|---|
| IUPAC name Tetraethyl orthosilicate | |
| Other names tetraethoxysilane; ethyl silicate, tetra-; silicic acid tetraethyl ester; silicon(IV) ethoxide; TEOS; tetraethyl silicate (ortho-) | |
| Identifiers | |
| 3D model (JSmol) | |
| ChemSpider | |
| ECHA InfoCard | 100.000.986 | 
| PubChem CID | |
| UNII | |
| CompTox Dashboard (EPA) | |
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| Properties | |
| SiC8H20O4 | |
| Molar mass | 208.33 g⋅mol−1 | 
| Appearance | Colourless liquid | 
| Odor | Sharp, alcohol-like | 
| Density | 0.933 g/mL at 20 °C | 
| Melting point | −77 °C (−107 °F; 196 K) | 
| Boiling point | 168 to 169 °C (334 to 336 °F; 441 to 442 K) | 
| Reacts with water, soluble in ethanol, and 2-propanol | |
| Vapor pressure | 1 mmHg | 
| Hazards | |
| Occupational safety and health (OHS/OSH): | |
| Main hazards | Flammable, harmful by inhalation | 
| Flash point | 45 °C (113 °F; 318 K) | 
| Lethal dose or concentration (LD, LC): | |
| LD50 (median dose) | 6270 mg/kg (rat, oral) | 
| LCLo (lowest published) | 
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| NIOSH (US health exposure limits): | |
| PEL (Permissible) | TWA 100 ppm (850 mg/m3) | 
| REL (Recommended) | TWA 10 ppm (85 mg/m3) | 
| IDLH (Immediate danger) | 700 ppm | 
| Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). Infobox references | |
Tetraethyl orthosilicate, formally named tetraethoxysilane (TEOS), ethyl silicate is the organic chemical compound with the formula Si(OC2H5)4. TEOS is a colorless liquid. It degrades in water. TEOS is the ethyl ester of orthosilicic acid, Si(OH)4. It is the most prevalent alkoxide of silicon.
TEOS is a tetrahedral molecule. Like its many analogues, it is prepared by alcoholysis of silicon tetrachloride:
- SiCl4 + 4 EtOH → Si(OEt)4 + 4 HCl
where Et is the ethyl group, C2H5, and thus EtOH is ethanol.