Tetrataenite

Tetrataenite
Silvery-bright tetrataenite crystals
General
CategoryNative element minerals
FormulaFeNi
IMA symbolTtae
Strunz classification1.AE.10
Crystal systemTetragonal
Crystal classDomatic (m)
(same H-M symbol)
Space groupP4/mmm
Unit cell22.92 ų
Identification
Formula mass57.27 gm
Colorgray white, silver white
Crystal habitGranular – Common texture observed in granite and other igneous rock
Cleavagenone
Fracturemalleable
Mohs scale hardness3.5
Lustermetallic
Streakgray
Diaphaneityopaque
Density8.275
Common impuritiesCo, Cu, P
References

Tetrataenite is a native metal alloy composed of chemically-ordered L10-type FeNi, recognized as a mineral in 1980. The mineral is named after its tetragonal crystal structure and its relation to the iron-nickel alloy, taenite, which is chemically disordered (A1) phase with an underlying fcc lattice. Tetrataenite is one of the mineral phases found in meteoric iron. Before its discovery in meteoritic samples, experimental synthesis of the L10 phase was first reported in 1962 by Louis Néel and co-workers, following neutron irradiation of a chemically disordered FeNi sample under an applied magnetic field. Compared to the magnetically soft, chemically disordered A1 phase (taenite), the tetragonal L10 structure of tetrataenite leads to good hard magnetic properties, including a large uniaxial magnetocrystalline anisotropy energy. Consequently, it is under consideration for applications as a rare-earth-free permanent magnet.