Thulium(III) oxalate

Thulium(III) oxalate
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.019.898
EC Number
  • 221-887-2
  • InChI=1S/3C2H2O4.2Tm/c3*3-1(4)2(5)6;;/h3*(H,3,4)(H,5,6);;/q;;;2*+3/p-6
    Key: BSCZSHAJTJRUPP-UHFFFAOYSA-H
  • [Tm+3].[Tm+3].[O-]C(=O)C(=O)[O-].[O-]C(=O)C(=O)[O-].[O-]C(=O)C(=O)[O-]
Properties
Tm2(C2O4)3
Appearance solid
Hazards
GHS labelling:
Warning
H302, H312
P264, P270, P280, P301+P317, P302+P352, P317, P321, P330, P362+P364, P501
Related compounds
Other cations
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Infobox references

Thulium(III) oxalate is the oxalate of thulium with the chemical formula Tm2(C2O4)3. Its hydrate can be prepared by reacting an aqueous solution of thulium(III) chloride and a benzene solution of dimethyl oxalate. Its pentahydrate is decomposed by heat to obtain the dihydrate, which is further heated to obtain thulium(III) oxide. It reacts with hydrochloric acid to obtain H[Tm(C2O4)2]·6H2O.