Trimethylsilyl chloride

Trimethylsilyl chloride
Names
Preferred IUPAC name
Chlorotri(methyl)silane
Other names
Trimethylsilyl chloride
Chlorotrimethylsilane
TMSCl
Trimethylchlorosilane
TMCS
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.000.819
EC Number
  • 200-900-5
RTECS number
  • VV2710000
UNII
UN number 1298
  • InChI=1S/C3H9ClSi/c1-5(2,3)4/h1-3H3 Y
    Key: IJOOHPMOJXWVHK-UHFFFAOYSA-N Y
  • C[Si](C)(C)Cl
Properties
C3H9SiCl
Molar mass 108.64 g/mol
Appearance Colorless liquid, fumes in moist air
Density 0.856 g/cm3, liquid
Melting point −40 °C (−40 °F; 233 K)
Boiling point 57 °C (135 °F; 330 K)
Reacts
−77.36·10−6 cm3/mol
Structure
Tetrahedral at Si
Hazards
GHS labelling:
Danger
H225, H301, H312, H314, H331, H351
P201, P202, P210, P233, P240, P241, P242, P243, P260, P261, P264, P270, P271, P280, P281, P301+P310, P301+P330+P331, P302+P352, P303+P361+P353, P304+P340, P305+P351+P338, P308+P313, P310, P311, P312, P321, P322, P330, P363, P370+P378, P403+P233, P403+P235, P405, P501
NFPA 704 (fire diamond)
3
3
2
Flash point −28 °C (−18 °F; 245 K)
400 °C (752 °F; 673 K)
Related compounds
Related halosilanes
Trimethylsilyl fluoride
Trimethylsilyl bromide
Trimethylsilyl iodide
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Y verify (what is YN ?)
Infobox references

Trimethylsilyl chloride, also known as chlorotrimethylsilane is an organosilicon compound (silyl halide), with the formula (CH3)3SiCl, often abbreviated Me3SiCl or TMSCl. It is a colourless volatile liquid that is stable in the absence of water. It is widely used in organic chemistry.