Triphenylstibine

Triphenylstibine
Names
Preferred IUPAC name
Triphenylstibane
Other names
Triphenylantimony
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.009.125
EC Number
  • 210-037-6
RTECS number
  • WJ1400000
UNII
  • InChI=1S/3C6H5.Sb/c3*1-2-4-6-5-3-1;/h3*1-5H; Y
    Key: HVYVMSPIJIWUNA-UHFFFAOYSA-N Y
  • InChI=1/3C6H5.Sb/c3*1-2-4-6-5-3-1;/h3*1-5H;/rC18H15Sb/c1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18/h1-15H
    Key: HVYVMSPIJIWUNA-KWOBPOEBAA
  • c3c([Sb](c1ccccc1)c2ccccc2)cccc3
Properties
C18H15Sb
Molar mass 353.07 g/mol
Appearance Colourless solid
Density 1.53 g/cm3
Melting point 52 to 54 °C (126 to 129 °F; 325 to 327 K)
Boiling point 377 °C (711 °F; 650 K)
insoluble
Structure
trigonal pyramidal
Related compounds
Related compounds
Triphenylamine
Triphenylphosphine
Triphenylarsine
Stibine
Hazards
Occupational safety and health (OHS/OSH):
Main hazards
mildly toxic
GHS labelling:
Danger
H301, H302, H332, H411
P261, P264, P270, P271, P273, P301+P310, P301+P312, P304+P312, P304+P340, P312, P330, P391, P405
NFPA 704 (fire diamond)
1
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Y verify (what is YN ?)
Infobox references

Triphenylstibine is the chemical compound with the formula Sb(C6H5)3, which is often abbreviated SbPh3, This colourless solid is a common organoantimony(III) compound. It serves as a ligand in coordination chemistry and as a reagent in organic synthesis.

Like the related molecules triphenylamine, triphenylphosphine and triphenylarsine, SbPh3 is pyramidal with a propeller-like arrangement of the phenyl groups. The Sb-C distances average 2.14-2.17 Å and the C-Sb-C angles are 95°.