Amino radical
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| Names | |||
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| IUPAC name Azanyl; Aminyl | |||
| Systematic IUPAC name Azanyl (substitutive) Dihydridonitrogen(•) (additive) | |||
| Other names Amidogen; Amino radical | |||
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| Properties | |||
| NH 2• | |||
| Molar mass | 16.0226 g mol−1 | ||
| Thermochemistry | |||
| Std molar entropy (S⦵298) | 194.71 J K−1 mol−1 | ||
| Std enthalpy of formation (ΔfH⦵298) | 190.37 kJ mol−1 | ||
| Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). Infobox references | |||
In chemistry, the amino radical, ·NH2, also known as the aminyl or azanyl, is the neutral form of the amide ion (NH−2). Aminyl radicals are highly reactive and consequently short-lived, like most radicals; however, they form an important part of nitrogen chemistry. In sufficiently high concentration, amino radicals dimerise to form hydrazine. While NH2 as a functional group is common in nature, forming a part of many compounds (e.g. the phenethylamines), the radical cannot be isolated in its free form.