Chlorosulfuric acid
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| Names | |||
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| IUPAC name
Sulfurochloridic acid | |||
| Other names
Chlorosulfuric acid, Chlorosulfonic acid, Chlorosulphonic acid, Chlorinesulfonic acid, Chlorinesulphonic acid, Chloridosulfonic acid, Chloridosulphonic acid, Sulfuric chlorohydrin | |||
| Identifiers | |||
3D model (JSmol) |
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| ChemSpider | |||
| ECHA InfoCard | 100.029.304 | ||
| EC Number |
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PubChem CID |
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| RTECS number |
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| UNII | |||
| UN number | 1754 | ||
CompTox Dashboard (EPA) |
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| Properties | |||
| HSO3Cl | |||
| Molar mass | 116.52 g mol−1 | ||
| Appearance | colorless liquid, but commercial samples usually are pale brown | ||
| Density | 1.753 g cm−3 | ||
| Melting point | −80 °C (−112 °F; 193 K) | ||
| Boiling point | 151 to 152 °C (304 to 306 °F; 424 to 425 K) (755 mmHg or 100.7 kPa) | ||
| hydrolysis | |||
| Solubility in other solvents | reacts with alcohols soluble in chlorocarbons | ||
| Acidity (pKa) | −5.9 (in CF3CO2H) | ||
Refractive index (nD) |
1.433 | ||
| Structure | |||
| tetrahedral | |||
| Hazards | |||
| GHS labelling: | |||
| Danger | |||
| H314, H335 | |||
| P260, P261, P264, P271, P280, P301+P330+P331, P303+P361+P353, P304+P340, P305+P351+P338, P310, P312, P321, P363, P403+P233, P405, P501 | |||
| NFPA 704 (fire diamond) | |||
| Safety data sheet (SDS) | ICSC 1039 | ||
| Related compounds | |||
Related compounds |
Sulfuryl chloride Sulfuric acid | ||
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Infobox references | |||
Chlorosulfuric acid (IUPAC name: sulfurochloridic acid) is the inorganic compound with the formula HSO3Cl. It is also known as chlorosulfonic acid, being the sulfonic acid of chlorine. It is a distillable, colorless liquid which is hygroscopic and a powerful lachrymator. Commercial samples usually are pale brown or straw colored.
Salts and esters of chlorosulfuric acid are known as chlorosulfates.