Sulfuric acid

Sulfuric acid
Space-filling model
Ball-and-stick model
bondlength
S=O 142.2 pm
SO 157.4 pm
OH 97 pm
Names
IUPAC name
Sulfuric acid
Other names
  • Oil of vitriol
  • Hydrogen sulfate
  • Dihydrogen sulfate
Identifiers
3D model (JSmol)
ChEBI
ChEMBL
ChemSpider
ECHA InfoCard 100.028.763
EC Number
  • 231-639-5
E number E513 (acidity regulators, ...)
2122
KEGG
RTECS number
  • WS5600000
UNII
UN number 1830
  • InChI=1S/H2O4S/c1-5(2,3)4/h(H2,1,2,3,4) Y
    Key: QAOWNCQODCNURD-UHFFFAOYSA-N Y
  • InChI=1/H2O4S/c1-5(2,3)4/h(H2,1,2,3,4)
    Key: QAOWNCQODCNURD-UHFFFAOYAC
  • OS(=O)(=O)O
Properties
H2SO4, sometimes expressed (HO)2SO2
Molar mass 98.079 g/mol
Appearance Colorless viscous liquid
Odor Odorless
Density 1.8302 g/cm3, liquid
Melting point 10.31 °C (50.56 °F; 283.46 K)
Boiling point 337 °C (639 °F; 610 K)
When sulfuric acid is above 300 °C (572 °F; 573 K), it gradually decomposes to SO3 + H2O
miscible, exothermic
Vapor pressure 0.001 mmHg (20 °C)
Acidity (pKa) pKa1 = −2.8
pKa2 = 1.99
Conjugate base Bisulfate
Viscosity 26.7 cP (20 °C)
Structure
monoclinic
C2/c
a = 818.1(2) pm, b = 469.60(10) pm, c = 856.3(2) pm
α = 90°, β = 111.39(3)
°, γ = 90°
4
Thermochemistry
157 J/(mol·K)
−814 kJ/mol
56 kJ/mol
Hazards
GHS labelling:
Danger
H314
P260, P264, P280, P301+P330+P331, P303+P361+P353, P304+P340, P305+P351+P338, P310, P321, P363, P405, P501
NFPA 704 (fire diamond)
Flash point Non-flammable
15 mg/m3 (IDLH), 1 mg/m3 (TWA), 2 mg/m3 (STEL)
Lethal dose or concentration (LD, LC):
2140 mg/kg (rat, oral)
  • 50 mg/m3 (guinea pig, 8 hr)
  • 510 mg/m3 (rat, 2 hr)
  • 320 mg/m3 (mouse, 2 hr)
  • 18 mg/m3 (guinea pig)
87 mg/m3 (guinea pig, 2.75 hr)
NIOSH (US health exposure limits):
PEL (Permissible)
TWA 1 mg/m3
REL (Recommended)
TWA 1 mg/m3
IDLH (Immediate danger)
15 mg/m3
Related compounds
Related strong acids
Related compounds
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
N verify (what is YN ?)
Infobox references

Sulfuric acid (American spelling and the preferred IUPAC name) or sulphuric acid (Commonwealth spelling), known in antiquity as oil of vitriol, is a mineral acid composed of the elements sulfur, oxygen, and hydrogen, with the molecular formula H2SO4. It is a colorless, odorless, and viscous liquid that is miscible with water.

Pure sulfuric acid does not occur naturally due to its strong affinity to water vapor; it is hygroscopic and readily absorbs water vapor from the air. Concentrated sulfuric acid is a strong oxidant with powerful dehydrating properties, making it highly corrosive towards other materials, from rocks to metals. Phosphorus pentoxide is a notable exception in that it is not dehydrated by sulfuric acid but, to the contrary, dehydrates sulfuric acid to sulfur trioxide. Upon addition of sulfuric acid to water, a considerable amount of heat is released; thus, the reverse procedure of adding water to the acid is generally avoided since the heat released may boil the solution, spraying droplets of hot acid during the process. Upon contact with body tissue, sulfuric acid can cause severe acidic chemical burns and secondary thermal burns due to dehydration. Dilute sulfuric acid is substantially less hazardous without the oxidative and dehydrating properties; though, it is handled with care for its acidity.

Many methods for its production are known, including the contact process, the wet sulfuric acid process, and the lead chamber process. Sulfuric acid is also a key substance in the chemical industry. It is most commonly used in fertilizer manufacture but is also important in mineral processing, oil refining, wastewater treating, and chemical synthesis. It has a wide range of end applications, including in domestic acidic drain cleaners, as an electrolyte in lead-acid batteries, as a dehydrating compound, and in various cleaning agents. Sulfuric acid can be obtained by dissolving sulfur trioxide in water.