Cobalt(II) cyanide

Cobalt(II) cyanide
Names
IUPAC name
Cobalt(II) cyanide
Other names
cobaltous cyanide
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.008.028
UNII
  • InChI=1S/2CN.Co/c2*1-2;/q2*-1;+2 Y
    Key: CWZOMTYLSNXUEL-UHFFFAOYSA-N Y
  • InChI=1/2CN.Co/c2*1-2;/q2*-1;+2
    Key: CWZOMTYLSNXUEL-UHFFFAOYAR
  • [Co+2].[C-]#N.[C-]#N
Properties
Co(CN)2
Molar mass 110.968 g/mol
Appearance deep-blue powder
hygroscopic
Density 1.872 g/cm3 (anhydrous)
Melting point 220 °C (428 °F; 493 K) (decomposes)
insoluble
Solubility dihydrate
degraded with dissolution by NaCN, KCN, NH4OH, HCl
+3825·10−6 cm3/mol
Related compounds
Other anions
Cadmium chloride,
Cadmium iodide
Other cations
Zinc cyanide,
Calcium cyanide,
Magnesium cyanide
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
N verify (what is YN ?)
Infobox references

Cobalt(II) cyanide is the inorganic compound with the empirical formula Co(CN)2 and structural formula Co3[Co(CN)5]2. It is a coordination polymer that has attracted intermittent attention over many years in the areas of inorganic synthesis and homogeneous catalysis. The anhydrous and octahydrate forms are both blue solids insoluble in water.