Digallane
|
| |||
| Names | |||
|---|---|---|---|
| IUPAC name
digallane(6) | |||
| Other names
Di-μ-hydrido-tetrahydridodigallium Gallane dimer | |||
| Identifiers | |||
3D model (JSmol) |
|||
| ChemSpider | |||
| |||
| |||
| Properties | |||
| Ga2H6 | |||
| Molar mass | 145.494 g/mol | ||
| Appearance | White solid or colorless gas | ||
| Melting point | −50 °C (−58 °F; 223 K) (sublimes) | ||
| Boiling point | 0 °C (32 °F; 273 K) (decomposes) | ||
| Reacts to form gallium(III) hydroxide | |||
| Related compounds | |||
Related compounds |
|||
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Infobox references | |||
Digallane (systematically named digallane(6)) is an inorganic compound with the chemical formula GaH2(H)2GaH2 (also written [{GaH2(μ-H)}2] or [Ga2H6]). It is the dimer of the monomeric compound gallane. The eventual preparation of the pure compound, reported in 1989, was hailed as a "tour de force." Digallane had been reported as early as 1941 by Wiberg; however, this claim could not be verified by later work by Greenwood and others. This compound is a colorless gas that decomposes above 0 °C.