Digallane

Digallane
Names
IUPAC name
digallane(6)
Other names
Di-μ-hydrido-tetrahydridodigallium
Gallane dimer
Identifiers
3D model (JSmol)
ChemSpider
  • InChI=1S/2Ga.6H
    Key: GFQCQFDOQMRGIQ-UHFFFAOYSA-N
  • [GaH2]1[H] [GaH2] [H]1
Properties
Ga2H6
Molar mass 145.494 g/mol
Appearance White solid or colorless gas
Melting point −50 °C (−58 °F; 223 K) (sublimes)
Boiling point 0 °C (32 °F; 273 K) (decomposes)
Reacts to form gallium(III) hydroxide
Related compounds
Related compounds
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Infobox references

Digallane (systematically named digallane(6)) is an inorganic compound with the chemical formula GaH2(H)2GaH2 (also written [{GaH2(μ-H)}2] or [Ga2H6]). It is the dimer of the monomeric compound gallane. The eventual preparation of the pure compound, reported in 1989, was hailed as a "tour de force." Digallane had been reported as early as 1941 by Wiberg; however, this claim could not be verified by later work by Greenwood and others. This compound is a colorless gas that decomposes above 0 °C.