Hübnerite

Hubnerite
General
CategoryOxide minerals
FormulaMnWO4
IMA symbolHbr
Strunz classification4.DB.30
Crystal systemMonoclinic
Crystal classPrismatic (2/m)
(same H-M symbol)
Space groupP21/c
Unit cella = 4.86, b = 5.78
c = 5.02 [Å]; β = 90.816°, Z = 4
Identification
ColorYellowish brown to reddish brown, blackish brown, black; Deep red internal reflections in reflected light
Crystal habitPrismatic striated crystals, tabular to flattened, in radiating groups
TwinningContact twins
CleavagePerfect on {010}
FractureIrregular/uneven
TenacityBrittle
Mohs scale hardness4–4+12
LusterMetallic to adamantine towards resinous.
StreakYellow to reddish brown, greenish gray
DiaphaneityTransparent to translucent
Specific gravity7.12–7.18
Optical propertiesBiaxial (+)
Refractive indexnα=2.17–2.2, nβ=2.22, nγ=2.3–2.32
Birefringence0.1200–0.1300
PleochroismPerceptible; X = yellow to green, red-orange; Y = yellowish brown to greenish yellow, red-orange to red; Z = green; brick-red to red
2V angle73° measured
References

Hübnerite or hubnerite is a mineral consisting of manganese tungsten oxide (chemical formula MnWO4). It is the manganese endmember of the manganeseiron wolframite solid solution series. It forms reddish brown to black monoclinic prismatic submetallic crystals. The crystals are typically flattened and occur with fine striations. It has a high specific gravity of 7.15 and a Mohs hardness of 4.5. It is transparent to translucent with perfect cleavage. Refractive index values are nα = 2.170 – 2.200, nβ = 2.220, and nγ = 2.300 – 2.320.

Typical occurrence is in association with high-temperature hydrothermal vein deposits and altered granites with greisen, granite pegmatites and in alluvial deposits. It occurs associated with cassiterite, arsenopyrite, molybdenite, tourmaline, topaz, rhodochrosite and fluorite.

It was first described in 1865 for an occurrence in the Erie and Enterprise veins, Mammoth district, Nye County, Nevada, and named after the German mining engineer and metallurgist, Adolf Hübner from Freiberg, Saxony.