Rubidium ozonide
| Identifiers | |
|---|---|
| 3D model (JSmol) | |
| 
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| Properties | |
| O3Rb | |
| Molar mass | 133.465 g·mol−1 | 
| Appearance | Dark red or brownish red crystals | 
| Related compounds | |
| Other anions | Rubidium fluoride Rubidium chloride Rubidium bromide Rubidium iodide | 
| Other cations | Sodium ozonide Potassium ozonide Caesium ozonide | 
| Rubidium suboxide Rubidium oxide Rubidium sesquioxide Rubidium peroxide Rubidium superoxide | |
| Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). Infobox references | |
Rubidium ozonide is an oxygen rich compound of rubidium. It is an ozonide, meaning it contains the ozonide anion (O3−).
It can be created by reacting rubidium superoxide (RbO2) with ozone (O3) in a liquid ammonia solution.
- RbO2 + O3 → RbO3 + O2
The chemical forms in two crystal structures, the low temperature α-RbO3 (P21), and β-RbO3 (P21/c) Detailed structural analysis finds the ozonide anions are significantly off-center from the surrounding rubidium atoms.
Since ozonide anion is magnetic, electron paramagnetic resonance measurements of rubidium ozonide have determined the g-values of the ozonide anion.