Tantalum(V) chloride

Tantalum(V) chloride
  Tantalum, Ta;   Chlorine, Cl
Names
IUPAC names
Tantalum(V) chloride
Tantalum pentachloride
Identifiers
  • 7721-01-9 TaCl5 Y
  • 17499-29-5 Ta2Cl10 N
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.028.869
EC Number
  • 231-755-6
UNII
  • Key: OEIMLTQPLAGXMX-UHFFFAOYSA-I
  • InChI=1S/5ClH.Ta/h5*1H;/q;;;;;+5/p-5
  • Cl[Ta](Cl)(Cl)(Cl)Cl
Properties
TaCl5
Molar mass 358.213 g/mol
Appearance white monoclinic crystals
Density 3.68 g/cm3
Melting point 216 °C (421 °F; 489 K)
Boiling point 239.4 °C (462.9 °F; 512.5 K) (decomposes)
reacts
Solubility chloroform, CCl4
+140.0×10−6 cm3/mol
Structure
Monoclinic, mS72
C2/m, No. 12
Thermochemistry
221.75 J K−1 mol−1
−858.98 kJ/mol
Hazards
GHS labelling:
Danger
H302, H314, H335
P260, P264+P265, P270, P271, P280, P301+P317, P301+P330+P331, P302+P361+P354, P304+P340, P305+P351+P338, P305+P354+P338, P310, P316, P330, P363, P403+P233, P405, P501
NFPA 704 (fire diamond)
3
0
0
Flash point Non-flammable
Lethal dose or concentration (LD, LC):
1900 mg/kg (oral, rat)
Safety data sheet (SDS) External SDS
Related compounds
Other anions
Other cations
Related compounds
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
N verify (what is YN ?)
Infobox references

Tantalum(V) chloride, also known as tantalum pentachloride, is an inorganic compound with the formula TaCl5. It takes the form of a white powder, and is commonly used as a starting material in tantalum chemistry. It readily hydrolyzes to form tantalum(V) oxytrichloride (TaOCl3) and eventually tantalum pentoxide (Ta2O5); this requires that it be synthesised and manipulated under anhydrous conditions, using air-free techniques.