Methanesulfonic acid
| Names | |
|---|---|
| Preferred IUPAC name
Methanesulfonic acid | |
| Other names
Methylsulfonic acid, MSA; Mesylic acid | |
| Identifiers | |
3D model (JSmol) |
|
| 1446024 | |
| ChEBI | |
| ChemSpider | |
| ECHA InfoCard | 100.000.817 |
| EC Number |
|
| 1681 | |
PubChem CID |
|
| UNII | |
| UN number | 2585 |
CompTox Dashboard (EPA) |
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| |
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| Properties | |
| CH4O3S | |
| Molar mass | 96.10 g·mol−1 |
| Appearance | Clear, colourless liquid |
| Density | 1.48 g/cm3 |
| Melting point | 17 to 19 °C (63 to 66 °F; 290 to 292 K) |
| Boiling point | 167 °C (333 °F; 440 K) at 10 mmHg, 122 °C/1 mmHg |
| miscible | |
| Solubility | Miscible with methanol, diethyl ether. Immiscible with hexane |
| log P | −2.424 |
| Acidity (pKa) | −1.9 |
| Hazards | |
| GHS labelling: | |
| Danger | |
| H314 | |
| P260, P264, P280, P301+P330+P331, P303+P361+P353, P304+P340, P305+P351+P338, P310, P321, P363, P405, P501 | |
| Safety data sheet (SDS) | Oxford MSDS |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Infobox references | |
Methanesulfonic acid (MsOH, MSA) or methanesulphonic acid (in British English) is an organosulfuric, colorless liquid with the molecular formula CH3SO3H and structure H3C−S(=O)2−OH. It is the simplest of the alkylsulfonic acids (R−S(=O)2−OH). Salts and esters of methanesulfonic acid are known as mesylates (or methanesulfonates, as in ethyl methanesulfonate). It is hygroscopic in its concentrated form. Methanesulfonic acid can dissolve a wide range of metal salts, many of them in significantly higher concentrations than in hydrochloric acid (HCl) or sulfuric acid (H2SO4).