Sodium chlorate
| Unit cell of sodium chlorate | |
| Names | |
|---|---|
| IUPAC name Sodium chlorate | |
| Other names Sodium chlorate(V) | |
| Identifiers | |
| 3D model (JSmol) | |
| ChEBI | |
| ChemSpider | |
| ECHA InfoCard | 100.028.989 | 
| EC Number | 
 | 
| KEGG | |
| MeSH | Sodium+chlorate | 
| PubChem CID | |
| RTECS number | 
 | 
| UNII | |
| UN number | 1495, 2428 | 
| CompTox Dashboard (EPA) | |
| 
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| 
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| Properties | |
| NaClO3 | |
| Molar mass | 106.44 g mol−1 | 
| Appearance | Colorless or white solid, hygroscopic | 
| Odor | Odorless | 
| Density | 2.49 g/cm3 (15 °C) 2.54 g/cm3 (20.2 °C) | 
| Melting point | 248–261 °C (478–502 °F; 521–534 K) | 
| Boiling point | 300–400 °C (572–752 °F; 573–673 K) decomposes | 
| 79 g/100 mL (0 °C) 89 g/100 mL (10 °C) 105.7 g/100 mL (25 °C) 125 g/100 mL (40 °C) 220.4 g/100 mL (100 °C) | |
| Solubility | Soluble in glycerol, hydrazine, methanol Slightly soluble in ethanol, ammonia | 
| Solubility in acetone | Sparingly soluble | 
| Solubility in glycerol | 20 g/100 g (15.5 °C) | 
| Solubility in ethanol | 14.7 g/100 g | 
| Vapor pressure | <0.35 mPa | 
| −34.7·10−6 cm3/mol | |
| Refractive index (nD) | 1.515 (20 °C) | 
| Structure | |
| cubic | |
| P213 | |
| a = 6.57584 Å | |
| Formula units (Z) | 4 | 
| Thermochemistry | |
| Heat capacity (C) | 104.6 J/mol·K | 
| Std molar entropy (S⦵298) | 129.7 J/mol·K | 
| Std enthalpy of formation (ΔfH⦵298) | −365.4 kJ/mol | 
| Gibbs free energy (ΔfG⦵) | −275 kJ/mol | 
| Hazards | |
| GHS labelling: | |
| Danger | |
| H271, H302, H411 | |
| P220, P273 | |
| NFPA 704 (fire diamond) | |
| Flash point | Non-flammable | 
| Lethal dose or concentration (LD, LC): | |
| LD50 (median dose) | 600 mg/kg (rats, oral) 700 mg/kg (dogs, oral) | 
| Safety data sheet (SDS) | ICSC 1117 | 
| Related compounds | |
| Other anions | Sodium chloride Sodium hypochlorite Sodium chlorite Sodium perchlorate Sodium bromate Sodium iodate | 
| Other cations | Ammonium chlorate Potassium chlorate Barium chlorate | 
| Related compounds | Chloric acid | 
| Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). Infobox references | |
Sodium chlorate is an inorganic compound with the chemical formula NaClO3. It is a white crystalline powder that is readily soluble in water. It is hygroscopic. It decomposes above 300 °C to release oxygen and leaves sodium chloride. Several hundred million tons are produced annually, mainly for applications in bleaching pulp to produce high brightness paper.